FRET-Mediated Collective Blinking of Self-Assembled Stacks of CdSe Semiconducting Nanoplatelets
نویسندگان
چکیده
Förster resonant energy transfer (FRET) can be an efficient mechanism between densely packed fluorescent emitters. It plays a key role in photosynthesis but may also detrimental. In optoelectronic devices for instance, FRET funnels to quenching sites and favors losses. Here, we image individual self-assembled chains of stacked CdSe nanoplatelets demonstrate fluorescence intermittency (blinking) chain portions corresponding few tens platelets. This collective blinking is attributed the fluctuations quencher site, which excitons are transferred by migration from surrounding We develop analytical random walk model show that ensemble platelets quenched collectively single site provided its (nonradiative recombination) rate faster than geometric mean radiative recombination rate, would order (100 ps)−1.
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ژورنال
عنوان ژورنال: ACS Photonics
سال: 2023
ISSN: ['2330-4022']
DOI: https://doi.org/10.1021/acsphotonics.2c01441